In einem Inhaltsverzeichnis zu einer Vorlesung zum PC Praktikum steht neben dem Stichwort Anfangsgeschwindigkeit einer Reaktion der Begriff Fall-off Verhalten.
Was könnte damit gemeint sein? Hat jemand eine Idee?
Gruß
Benedikt
Alles, was ich finden konnte. Vielleicht hilft’s:
A ``fall-off’’ reaction is one in which the temperature and pressure are such that the reaction occurs between Arrhenius high-pressure and low-pressure limits, and thus is no longer solely dependent on temperature.
There are three methods of representing the rate expressions in this fall-off region. The simplest one is the Lindemann form. There are also two other related methods, the Troe method and the SRI method, that provide a more accurate description of the fall-off region.
Gruß
Jochen